Schematics of the two CO2 electrolysis cells utilized in this work. a Protochips Poseidon in-situ LP-(S)TEM holder consisting of a Pd decorated glassy carbon working electrode within a microchip electrochemical cell. b Two-compartment electrochemical cell consisting of a large-format Pd decorated glassy carbon working electrode for electrochemical CO2R activity and selectivity measurements. c SEM images of the in-situ TEM microchip working electrode coated with electrodeposited Pd particles. d Micrograph of the large-format glassy carbon electrode and SEM image of the electrodeposited Pd particles. e Cyclic voltammetry measurements of electrodeposited Pd particles measured in the in-situ TEM microchip electrochemical cell. f Cyclic voltammetry measurements of electrodeposited Pd particles measured in the two-compartment cell using the large-format electrode. Note that all cyclic voltammetry measurements were collected in N2-saturated 0.1 M KHCO3 at a scan rate of 50 mV/s. Credit: Nature Communications (2024). DOI: 10.1038/s41467-024-45096-3
Think of it as recycling on the nanoscale: a tantalizing electrochemical process that can harvest carbon before it becomes air pollution and restructure it into the components of everyday products.The drive to capture airborne carbon dioxide from industrial waste and make it into fuel and plastics is gaining momentum after a team of researchers based at McMaster University, working with computational chemistry experts at Copenhagen’s Danish Technical University, have uncovered precisely how the process works and where it bogs down.Their work is published in the journal Nature Communications.The researchers set out to resolve why synthetic materials that have been shown to catalyze and convert carbon dioxide break down too quickly for the process to be practical at an industrial level.Using extremely powerful magnification equipment at the Canadian Centre for Electron Microscopy (CCEM), which is based on McMaster’s campus, the researchers were able to capture the chemical reaction at nanoscale—billionths of a meter—allowing them to study both the conversion process and understand how the catalyst breaks down under operating conditions.Lead author Ahmed Abdellah spent years developing the techniques that made it possible to observe the process, using an electrochemical reactor small enough to work under the electron microscopes at the center.
“It’s exciting for us that this is the first time anyone has been able to look at both the shapes of these structures and their crystal structures, to see how they evolve at the nanoscale,” says Abdellah, a former Ph.D. student in the chemical engineering lab of Drew Higgins and now a postdoctoral fellow at the CCEM.Higgins, a corresponding author of the paper, hopes the new information will facilitate the global effort to reduce carbon pollution by drawing carbon dioxide away from waste streams and instead recycling it to create useful products that would otherwise be produced from fossil fuels.”What we have found is that catalysts that can convert carbon dioxide into fuels and chemicals restructure quite rapidly under operating conditions. Their structures change and their properties change, right before our very eyes” Higgins says. “That dictates how efficient they are at converting carbon dioxide and how long they last. The catalysts eventually degrade and stop working and we want to know why they do that and how they do that so that we can develop strategies to improve their operational lifetimes.”Abdellah, Higgins and their colleagues are hopeful they and other researchers around the world can use the research results described in the new paper to make the reactive materials last longer and catalyze the process more efficiently, to allow the lab-based process to be scaled up for commercial use.Industries such as cement manufacturing, brewing and distilling, as well as chemical refineries, produce high volumes of readily retrievable carbon dioxide, Higgins explains, making them likely first targets for rolling out the technology once it is improved to the point where it is commercially viable.Other less concentrated forms of CO2 in industrial waste would come next.Though it’s a longshot today, Higgins says it’s possible the same technology could become efficient and stable enough to pull carbon dioxide from ambient air as “feedstock” for fuel and useful chemicals.”We’re still a little ways off, but progress has been very rapid in this field of research and development in the last five years or so,” Higgins says. “Ten years ago, people weren’t thinking about this kind of conversion, but now we’re starting to see promise. Efficiency and durability, though, just aren’t high enough yet. Once these bottlenecks are removed, this idea can really take off.”
