With scanning ultrafast electron microscopy, researchers unveil hot photocarrier transport properties of cubic boron

In a study that confirms its promise as the next-generation semiconductor material, UC Santa Barbara researchers have directly visualized the photocarrier transport properties of cubic boron arsenide single crystals.

“We were able to visualize how the charge moves in our sample,” said Bolin Liao, an assistant professor of mechanical engineering in the College of Engineering. Using the only scanning ultrafast electron microscopy (SUEM) setup in operation at a U.S. university, he and his team were able to make “movies” of the generation and transport processes of a photoexcited charge in this relatively little-studied III-V semiconductor material, which has recently been recognized as having extraordinary electrical and thermal properties. In the process, they found another beneficial property that adds to the material’s potential as the next great semiconductor.

Their research, conducted in collaboration with physics professor Zhifeng Ren’s group at the University of Houston, who specialize in fabricating high-quality single crystals of cubic boron arsenide, appears in the journal Matter.

‘Ringing the bell’

Boron arsenide is being eyed as a potential candidate to replace silicon, the computer world’s staple semiconductor material, due to its promising performance. For one thing, with an improved charge mobility over silicon, it easily conducts current (electrons and their positively charged counterpart, “holes”). However, unlike silicon, it also conducts heat with ease.

“This material actually has 10 times higher thermal conductivity than silicon,” Liao said. This heat conducting—and releasing—ability is particularly important as electronic components become smaller and more densely packed, and pooled heat threatens the devices’ performance, he explained.

“As your cellphones become more powerful, you want to be able to dissipate the heat, otherwise you have efficiency and safety issues,” he said. “Thermal management has been a challenge for a lot of microelectronic devices.”

What gives rise to the high thermal conductivity of this material, it turns out, can also lead to interesting transport properties of photocarriers, which are the charges excited by light, for example, in a solar cell. If experimentally verified, this would indicate that cubic boron arsenide can also be a promising material for photovoltaic and light detection applications. Direct measurement of photocarrier transport in cubic boron arsenide, however, has been challenging due to the small size of available high-quality samples.

The research team’s study combines two feats: The crystal growth skills of the University of Houston team, and the imaging prowess at UC Santa Barbara. Combining the abilities of the scanning electron microscope and femtosecond ultrafast lasers, the UCSB team built what is essentially an extremely fast, exceptionally high-resolution camera.

“Electron microscopes have very good spatial resolution—they can resolve single atoms with their sub-nanometer spatial resolution—but they’re typically very slow,” Liao said, noting this makes them excellent for capturing static images.

“With our technique, we couple this very high spatial resolution with an ultrafast laser, which acts as a very fast shutter, for extremely high time resolution,” Liao continued. “We’re talking about one picosecond—a millionth of a millionth of a second. So we can make movies of these microscopic energy and charge transport processes.” Originally invented at Caltech, the method was further developed and improved at UCSB from scratch and now is the only operational SUEM setup at an American university.

“What happens is that we have one pulse of this laser that excites the sample,” explained graduate student researcher Usama Choudhry, the lead author of the Matter paper. “You can think of it like ringing a bell; it’s a loud noise that slowly diminishes over time.” As they “ring the bell,” he explained, a second laser pulse is focused onto a photocathode (“electron gun”) to generate a short electron pulse to image the sample. They then scan the electron pulse over time to gain a full picture of the ring. “Just by taking a lot of these scans, you can get a movie of how the electrons and holes get excited and eventually go back to normal,” he said.

Among the things they observed while exciting their sample and watching the electrons return to their original state is how long the “hot” electrons persist.

“We found, surprisingly, the ‘hot’ electrons excited by light in this material can persist for much longer times than in conventional semiconductors,” Liao said. These “hot” carriers were seen to persist for more that 200 picoseconds, a property that is related to the same feature that is responsible for the material’s high thermal conductivity. This ability to host “hot” electrons for significantly longer amounts of time has important implications.

“For example, when you excite the electrons in a typical solar cell with light, not every electron has the same amount of energy,” Choudhry explained. “The high-energy electrons have a very short lifetime, and the low-energy electrons have a very long lifetime.” When it comes to harvesting the energy from a typical solar cell, he continued, only the low-energy electrons are efficiently being collected; the high-energy ones tend to lose their energy rapidly as heat. Because of the persistence of the high-energy carriers, if this material was used as a solar cell, more energy could efficiently be harvested from it.

With boron arsenide beating silicon in three relevant areas—charge mobility, thermal conductivity and hot photocarrier transport time—it has the potential to become the electronics world’s next state-of-the-art material. However, it still faces significant hurdles—fabrication of high-quality crystals in large quantities—before it can compete with silicon, enormous amounts of which can be manufactured relatively cheaply and with high quality. But Liao doesn’t see too much of a problem.

“Silicon is now routinely available because of years of investment; people started developing silicon around the 1930s and ’40s,” he said. “I think once people recognize the potential of this material, there will be more effort put into finding ways to grow and use it. UCSB is actually uniquely positioned for this challenge with strong expertise in semiconductor development.”

New data transmission record set using a single laser and a single optical chip

optical chip
Credit: Unsplash/CC0 Public Domain

An international group of researchers from Technical University of Denmark (DTU) and Chalmers University of Technology in Gothenburg, Sweden have achieved dizzying data transmission speeds and are the first in the world to transmit more than 1 petabit per second (Pbit/s) using only a single laser and a single optical chip.

1 petabit corresponds to 1 million gigabits.

In the experiment, the researchers succeeded in transmitting 1.8 Pbit/s, which corresponds to twice the total global Internet traffic. And only carried by the light from one optical source. The light source is a custom-designed optical chip, which can use the light from a single infrared laser to create a rainbow spectrum of many colors, i.e., many frequencies. Thus, the one frequency (color) of a single laser can be multiplied into hundreds of frequencies (colors) in a single chip.

All the colors are fixed at a specific frequency distance from each other—just like the teeth on a comb—which is why it is called a frequency comb. Each color (or frequency) can then be isolated and used to imprint data. The frequencies can then be reassembled and sent over an optical fiber, thus transmitting data. Even a huge volume of data, as the researchers have discovered.

One single laser can replace thousands

The experimental demonstration showed that a single chip could easily carry 1.8 Pbit/s, which—with contemporary state-of-the-art commercial equipment—would otherwise require more than 1,000 lasers.

Victor Torres Company, professor at Chalmers University of Technology, is head of the research group that has developed and manufactured the chip.

“What is special about this chip is that it produces a frequency comb with ideal characteristics for fiber-optical communications—it has high optical power and covers a broad bandwidth within the spectral region that is interesting for advanced optical communications,” says Victor Torres Company.

Interestingly enough, the chip was not optimized for this particular application.

“In fact, some of the characteristic parameters were achieved by coincidence and not by design,” says Victor Torres Company. “However, with efforts in my team, we are now capable to reverse engineer the process and achieve with high reproducibility microcombs for target applications in telecommunications.”

Enormous potential for scaling

In addition, the researchers created a computational model to examine theoretically the fundamental potential for data transmission with a single chip identical to the one used in the experiment. The calculations showed enormous potential for scaling up the solution.

Professor Leif Katsuo Oxenløwe, Head of the Center of Excellence for Silicon Photonics for Optical Communications (SPOC) at DTU, says:

“Our calculations show that—with the single chip made by Chalmers University of Technology, and a single laser—we will be able to transmit up to 100 Pbit/s. The reason for this is that our solution is scalable—both in terms of creating many frequencies and in terms of splitting the frequency comb into many spatial copies and then optically amplifying them, and using them as parallel sources with which we can transmit data. Although the comb copies must be amplified, we do not lose the qualities of the comb, which we utilize for spectrally efficient data transmission.”

This is how you pack light with data

Packing light with data is known as modulation. Here, the wave properties of light are utilized such as:

  • Amplitude (the height/strength of the waves)
  • Phase (the “rhythm” of the waves, where it is possible to make a shift so that a wave arrives either a little earlier or a little later than expected)
  • Polarization (the directions in which the waves spread).

By changing these properties, you create signals. The signals can be translated into either ones or zeros—and thus utilized as data signals.

Reduces Internet power consumption

The researchers’ solution bodes well for the future power consumption of the Internet.

“In other words, our solution provides a potential for replacing hundreds of thousands of the lasers located at Internet hubs and data centers, all of which guzzle power and generate heat. We have an opportunity to contribute to achieving an Internet that leaves a smaller climate footprint,” says Leif Katsuo Oxenløwe.

Even though the researchers have broken the petabit barrier for a single laser source and a single chip in their demonstration, there is still some development work ahead before the solution can be implemented in our current communication systems, according to Leif Katsuo Oxenløwe.

“All over the world, work is being done to integrate the laser source in the optical chip, and we’re working on that as well. The more components we can integrate in the chip, the more efficient the whole transmitter will be, i.e., laser, comb-creating chip, data modulators, and any amplifier elements. It will be an extremely efficient optical transmitter of data signals,” says Leif Katsuo Oxenløwe.

The research is published in Nature Photonics.

Navigating when GPS goes dark

Navigating when GPS goes dark
Cross-sectional renderings of the LPAI sensor head. a, Horizontal cross-section showing the cooling-beam and atom-detection channels with fixed optical components. The cooling-channel light is delivered to the sensor head via a polarization maintaining (PM) fiber from which a large collimated Gaussian beam (D1/e2≈28mm) is used for cooling. The beam is truncated to ≈ 19 mm-diameter through the fused silica viewport in the compact LPAI sensor head. The light then passes through a polarizer and a λ/4 waveplate before illuminating the grating chip. The GMOT atoms (solid red circle) form ≈ 3.5 mm from the grating surface. The atom-detection channel was designed to measure atomic fluorescence through a multimode-fiber-coupled avalanche photodiode (APD) module. b, Vertical cross-section of the sensor head showing the designed beam paths for Doppler-sensitive Raman. Cross-linearly-polarized Raman beams are launched from the same PM fiber and the two components are split by a polarizing beam splitter (PBS). Fixed optics route the Raman beams to the GMOT atoms (solid red circle) with opposite directions. Credit: Nature Communications (2022). DOI: 10.1038/s41467-022-31410-4

Words like “tough” or “rugged” are rarely associated with a quantum inertial sensor. The remarkable scientific instrument can measure motion a thousand times more accurately than the devices that help navigate today’s missiles, aircraft and drones. But its delicate, table-sized array of components that includes a complex laser and vacuum system has largely kept the technology grounded and confined to the controlled settings of a lab.

Jongmin Lee wants to change that.

The atomic physicist is part of a team at Sandia that envisions quantum inertial sensors as revolutionary, onboard navigational aids. If the team can reengineer the sensor into a compact, rugged device, the technology could safely guide vehicles where GPS signals are jammed or lost.

In a major milestone toward realizing their vision, the team has successfully built a cold-atom interferometer, a core component of quantum sensors, designed to be much smaller and tougher than typical lab setups. The team describes their prototype in the academic journal Nature Communications, showing how to integrate several normally separated components into a single monolithic structure. In doing so, they reduced the key components of a system that existed on a large optical table down to a sturdy package roughly the size of a shoebox.

“Very high sensitivity has been demonstrated in the lab, but the practical matters are, for real-world application, that people need to shrink down the size, weight and power, and then overcome various issues in a dynamic environment,” Jongmin said.

The paper also describes a roadmap for further miniaturizing the system using technologies under development.

The prototype, funded by Sandia’s Laboratory Directed Research and Development program, demonstrates significant strides toward moving advanced navigation tech out of the lab and into vehicles on the ground, underground, in the air and even in space.

Navigating when GPS goes dark
Concept of the compact light-pulse atom interferometer (LPAI) for high-dynamic conditions. a 3D rendering of the compact LPAI sensor head with fixed optical components and reliable optomechanical design. b Picture of the steady-state GMOT atoms in the sensor head.. Credit: Nature Communications (2022). DOI: 10.1038/s41467-022-31410-4

Ultrasensitive measurements drive navigational power

As a jet does a barrel roll through the sky, current onboard navigation tech can measure the aircraft’s tilts and turns and accelerations to calculate its position without GPS, for a time. Small measurement errors gradually push a vehicle off course unless it periodically syncs with the satellites, Jongmin said.

Quantum sensing would operate in the same way, but the much better accuracy would mean onboard navigation wouldn’t need to cross-check its calculations as often, reducing reliance on satellite systems.

Roger Ding, a postdoctoral researcher who worked on the project, said, “In principle, there are no manufacturing variations and calibrations,” compared to conventional sensors that can change over time and need to be recalibrated.

Aaron Ison, the lead engineer on the project, said to prepare the atom interferometer for a dynamic environment, he and his team used materials proven in extreme environments. Additionally, parts that are normally separate and freestanding were integrated together and fixed in place or were built with manual lockout mechanisms.

“A monolithic structure having as few bolted interfaces as possible was key to creating a more rugged atom interferometer structure,” Aaron said.

Furthermore, the team used industry-standard calculations called finite element analysis to predict that any deformation of the system in conventional environments would fall within required allowances. Sandia has not conducted mechanical stress tests or field tests on the new design, so further research is needed to measure the device’s strength.

“The overall small, compact design naturally leads towards a stiffer more robust structure,” Aaron said.

Navigating when GPS goes dark
Sandia atomic physicist Jongmin Lee examines the sensor head of a cold-atom interferometer that could help vehicles stay on course where GPS is unavailable. Credit: Bret Latter

Photonics light the way to a more miniaturized system

Most modern atom interferometry experiments use a system of lasers mounted to a large optical table for stability reasons, Roger said. Sandia’s device is comparatively compact, but the team has already come up with further design improvements to make the quantum sensors much smaller using integrated photonic technologies.

“There are tens to hundreds of elements that can be placed on a chip smaller than a penny,” said Peter Schwindt, the principal investigator on the project and an expert in quantum sensing.

Photonic devices, such as a laser or optical fiber, use light to perform useful work and integrated devices include many different elements. Photonics are used widely in telecommunications, and ongoing research is making them smaller and more versatile.

With further improvements, Peter thinks the space an interferometer needs could be as little as a few liters. His dream is to make one the size of a soda can.

In their paper, the Sandia team outlines a future design in which most of their laser setup is replaced by a single photonic integrated circuit, about eight millimeters on each side. Integrating the optical components into a circuit would not only make an atom interferometer smaller, it would also make it more rugged by fixing the components in place.

While the team can’t do this yet, many of the photonic technologies they need are currently in development at Sandia.

“This is a viable path to highly miniaturized systems,” Roger said.

Meanwhile, Jongmin said integrated photonic circuits would likely lower costs and improve scalability for future manufacturing.

“Sandia has shown an ambitious vision for the future of quantum sensing in navigation,” Jongmin said.

Exploring the hidden charm of quark-gluon plasma

ALICE explores hidden charm of quark-gluon plasma
Illustration of the effect of quark–gluon plasma on the formation of charmonia in lead-nuclei collisions. When the plasma temperature increases, the more weakly bound ψ(2S) state is more likely to be “screened”, and thus not form, due to the larger number of quarks and gluons in the plasma (the colored circles). The increase in the number of charm quarks and antiquarks (c and c̄) can lead to the formation of additional charmonia by quark recombination. Credit: ALICE collaboration

Quark–gluon plasma is an extremely hot and dense state of matter in which the elementary constituents—quarks and gluons—are not confined inside composite particles called hadrons, as they are in the protons and neutrons that make up the nuclei of atoms. Thought to have existed in the early universe, this special phase of matter can be recreated at the Large Hadron Collider (LHC) in collisions between lead nuclei.

A new analysis from the international ALICE collaboration at the LHC investigates how different bound states of a charm quark and its antimatter counterpart, also produced in these collisions, are affected by quark–gluon plasma. The results open new avenues for studying the strong interaction—one of the four fundamental forces of nature—in the extreme temperature and density conditions of quark–gluon plasma.

Bound states of a charm quark and a charm antiquark, known as charmonia or hidden-charm particles, are held together by the strong interaction and are excellent probes of quark–gluon plasma. In the plasma, their production is suppressed due to “screening” by the large number of quarks and gluons present in this form of matter.

The screening, and thus the suppression, increases with the temperature of the plasma and is expected to affect different charmonia to varying degrees. For example, the production of the ψ(2S) state, which is ten times more weakly bound and 20% more massive than the J/ψ state, is expected to be more suppressed than that of the J/ψ state.

This hierarchical suppression is not the only fate of charmonia in quark–gluon plasma. The large number of charm quarks and antiquarks in the plasma—up to about a hundred in head-on collisions—also gives rise to a mechanism, called recombination, that forms new charmonia and counters the suppression to a certain extent.

This process is expected to depend on the type and momentum of the charmonia, with the more weakly bound charmonia possibly being produced through recombination later in the evolution of the plasma, and charmonia with the lowest (transverse) momentum having the highest recombination rate.

Exploring the hidden charm of quark-gluon plasma
A lead–lead collision event recorded by ALICE in 2015. Credit: ALICE collaboration

Previous studies, which used data from CERN’s Super Proton Synchrotron and subsequently from the LHC, have shown that the production of the ψ(2S) state is indeed more suppressed than that of the J/ψ. ALICE has also previously provided evidence of the recombination mechanism in J/ψ production. But, until now, no studies of ψ(2S) production at low particle momentum had been precise enough to provide conclusive results in this momentum regime, preventing a complete picture of ψ(2S) production from being obtained.

The ALICE collaboration has now reported the first measurements of ψ(2S) production down to zero transverse momentum, based on lead–lead collision data from the LHC collected in 2015 and 2018.

The measurements show that, regardless of particle momentum, the ψ(2S) state is suppressed about two times more than the J/ψ. This is the first time that a clear hierarchy in suppression has been observed for the total production of charmonia at the LHC. A similar observation was previously reported by the LHC collaborations for bound states of a bottom quark and its antiquark.

When further studied as a function of particle momentum, the ψ(2S) suppression is seen to be reduced towards lower momentum. This feature, which was previously observed by ALICE for the J/ψ state, is a signature of the recombination process.

Future higher-precision studies of these and other charmonia using data from LHC Run 3, which started in July, may lead to a definitive understanding of the modification of hidden-charm particles and, as a result, of the strong interaction that holds them together, in the extreme environment of quark–gluon plasma.

Tapping hidden visual information: An all-in-one detector for thousands of colors

rainbows
Credit: Pixabay/CC0 Public Domain

Spectrometers are widely used throughout industry and research to detect and analyze light. Spectrometers measure the spectrum of light—its strength at different wavelengths, like the colors in a rainbow—and are an essential tool for identifying and analyzing specimens and materials. Integrated on-chip spectrometers would be of great benefit to a variety of technologies, including quality inspection platforms, security sensors, biomedical analyzers, health care systems, environmental monitoring tools, and space telescopes.

An international research team led by researchers at Aalto University has developed high-sensitivity spectrometers with high wavelength accuracy, high spectral resolution, and broad operation bandwidth, using only a single microchip-sized detector. The research behind this new ultra-miniaturized spectrometer was published today in the journal Science.

“Our single-detector spectrometer is an all-in-one device. We designed this optoelectronic-lab-on-a-chip with artificial intelligence replacing conventional hardware, such as optical and mechanical components. Therefore, our computational spectrometer does not require separate bulky components or array designs to disperse and filter light. It can achieve a high resolution comparable to benchtop systems but in a much smaller package,” says Postdoctoral Researcher Hoon Hahn Yoon.

“With our spectrometer, we can measure light intensity at each wavelength beyond the visible spectrum using a device at our fingertips. The device is entirely electrically controllable, so it has enormous potential for scalability and integration. Integrating it directly into portable devices such as smartphones and drones could advance our daily lives. Imagine that the next generation of our smartphone cameras could be fitted with hyperspectral cameras that outperform color cameras,” he adds.

Shrinking computational spectrometers is essential for their use in chips and implantable applications. Professor Zhipei Sun, the head of the research team, says, “Conventional spectrometers are bulky because they need optical and mechanical components, so their on-chip applications are limited. There is an emerging demand in this field to improve the performance and usability of spectrometers. From this point of view, miniaturized spectrometers are very important to offer high performance and new functions in all fields of science and industry.”

Professor Pertti Hakonen adds that “Finland and Aalto have invested in photonics research in recent years. For example, there has been great support from the Academy of Finland’s Center of Excellence on quantum technology, Flagship on Photonics Research and Innovation, InstituteQ, and the Otanano Infrastructure. Our new spectrometer is a clear demonstration of the success of these collaborative efforts. I believe that with further improvements in resolution and efficiency, these spectrometers could provide new tools for quantum information processing.”

Exploring the decay processes of a quantum state weakly coupled to a finite-size reservoir

Sketch of a quantum state (white dot) weakly coupled to the discrete levels of a chaotic quantum dot (black dots connected by lines). Credit: Micklitz et al

In quantum physics, Fermi’s golden rule, also known as the golden rule of time-dependent perturbation theory, is a formula that can be used to calculate the rate at which an initial quantum state transitions into a final state, which is composed of a continuum of states (a so-called “bath”). This valuable equation has been applied to numerous physics problems, particularly those for which it is important to consider how systems respond to imposed perturbations and settle into stationary states over time.

Fermi’s golden rule specifically applies to instances in which an initial  is weakly coupled to a continuum of other final states, which overlap its energy. Researchers at the Centro Brasileiro de Pesquisas Físicas, Princeton University, and Universität zu Köln have recently set out to investigate what happens when a quantum state is instead coupled to a set of discrete final states with a nonzero mean level spacing, as observed in recent many-body physics studies.

“The decay of a quantum state into some continuum of final states (i.e., a ‘bath’) is commonly associated with incoherent decay processes, as described by Fermi’s golden rule,” Tobias Micklitz, one of the researchers who carried out the study, told Phys.org. “A standard example for this is an excited atom emitting a photon into an infinite vacuum. Current date experimentations, on the other hand, routinely realize composite systems involving quantum states coupled to effectively finite size reservoirs that are composed of discrete sets of final states, rather than a continuum.”

While several past studies have identified systems in which quantum states are coupled to finite size reservoirs, understanding the conditions under which this happens, allowing the finite size reservoirs to effectively act as “baths” is a challenging task. The key objective of the recent work by Micklitz and his colleagues was to better understand the process through which a quantum state decays when coupled to a finite size .

“Our starting point was to consider generic finite size reservoirs lacking any specific symmetries,” Micklitz explained. “Such systems usually show quantum chaotic behavior and can be modeled by random matrices for which powerful analytical tools are available.”

To carry out their analyses, Micklitz and his colleagues used a combination of effective matrix integral techniques, which are commonly used in studies applying random matrix theory, a theory that summarizes the different properties of matrices with entries drawn randomly from different probability distributions. To benchmark the results of their analyses, they then used exact diagonalization, a powerful numerical technique often used by physicists to study individual quantum many-body systems.

“Initially we hadn’t expected the decay into a finite size reservoir to be described by such a complex time-dependence,” Micklitz said. “We found that the probability to reside in the weakly coupled level shows a non-motonous time-dependence with initial decay, followed by a raise, before saturating to a constant value. The temporal profile follows (in a large regime of parameters) the ‘spectral form factor,’ a well-studied object in the quantum chaos community, which encodes information on energy level correlations in the reservoir. This makes much sense in retrospective.”

Now published in Physical Review Letters, the recent study by this team of researchers offers a fully analytic description of a crucial and fundamental physics problem. More specifically, it offers a connection between the problem of how a quantum state decays into a set of discrete final states to the statistics associated with energy levels and wave functions in chaotic quantum systems.

“We relate the temporal profile of the probability of residence to the spectral form factor, and the ratio of the probability’s minimum and saturation values to the statistics of reservoir-eigenfunctions,” Micklitz added. “Our work focuses on a fundamental but also rather elementary example of relaxation into a finite size reservoir. We are now trying to address more complex systems, such as ensembles of spins coupled to a quantum dot. Hopefully, progress can be made using similar methods as those employed in our recent paper.”

Exploring light-driven molecular swing

Exploring light-driven molecular swing

Calculated coherence and energy transfer ratios. Calculated vibrational molecular coherence in the symmetric stretching vibrational mode of the DMSO2 molecule in solution displayed in a frame rotating with the vibrational eigenfrequency. The calculations are done with a the compressed pulse using the RWA, b the compressed pulse without the RWA, c the chirped pulse using the RWA, and d the chirped pulse without the RWA. The red curves include relaxation; the blue curves do not include relaxation. Each bump of the cycloid in b corresponds to one half-cycle of the electric field, showing that energy transfer from the excitation field to the molecular system is completed after 3 to 4 field cycles in the case of the FCE. In d, the time points that are maxima of CET(t) caused by the symmetric stretching vibration are marked with black dots. e Re-emitted (orange) and maximum absorbed (green) fraction of the impinging pulse energy versus concentration. The results were obtained from the impulsive-regime model (see Supplementary Information) with the FCE and ab initio Lorentz parameters. The solid lines include direct interactions with the surrounding water and the screening effect of the polarizable continuum, the dashed lines only the latter, and the dotted lines neither. For small concentrations, the maximum absorbed energy scales linearly with concentration. In contrast, the coherent re-emission, containing the spectroscopic information, scales quadratically with concentration. Credit: Nature Communications (2022). DOI: 10.1038/s41467-022-33477-5

When light impinges on molecules, it is absorbed and re-emitted. Advances in ultrafast laser technology have steadily improved the level of detail in studies of such light-matter interactions.

FRS, a laser spectroscopy method in which the electric field of laser pulses repeating millions of times per second is recorded with time resolution after passing through the sample, now provides even deeper insights: Scientists led by Prof. Dr. Regina de Vivie-Riedle (LMU/Department of Chemistry) and PD Dr. Ioachim Pupeza (LMU/Department of Physics, MPQ) show for the first time in theory and experiment how molecules gradually absorb the energy of the ultrashort light pulse in each individual optical cycle, and then release it again over a longer period of time, thereby converting it into spectroscopically meaningful light.

The study elucidates the mechanisms that fundamentally determine this energy transfer. It also develops and verifies a detailed quantum chemical model that can be used in the future to quantitatively predict even the smallest deviations from linear behavior.

A child on a swing sets it in motion with tilting movements of the body, which must be synchronized with the swing movement. This gradually adds energy to the swing, so that the deflection of the swing increases over time. Something similar happens when the alternating electromagnetic field of a short laser pulse interacts with a molecule, only about 100 trillion times faster: When the alternating field is synchronized with the vibrations between the atoms of the molecule, these vibration modes absorb more and more energy from the light pulse, and the vibration amplitude increases.

When the exciting field oscillations are over, the molecule continues to vibrate for a while—just like a swing after the person stops the tilting movements. Like an antenna, the slightly electrically charged atoms in motion then radiate a light field. Here, the frequency of the light field oscillation is determined by properties of the molecule such as atomic masses and bond strengths, which allows for an identification of the molecule.

Researchers from the attoworld team at MPQ and LMU, in collaboration with LMU researchers from the Department of Chemistry (Division of Theoretical Femtochemistry), have now distinguished these two constituent parts of the light field—on the one hand, the exciting light pulses, and on the other, the decaying light field oscillations—using time-resolved spectroscopy. In doing so, they investigated the behavior of organic molecules dissolved in water.

“While established laser spectroscopy methods usually only measure the spectrum and thus do not allow any information about the temporal distribution of the energy, our method can precisely track how the molecule absorbs a little more energy with each subsequent oscillation of the light field,” says Ioachim Pupeza, head of the experiment.

That the measurement method allows this temporal distinction is best illustrated by the fact that the scientists repeated the experiment, changing the duration of the exciting pulse but without changing its spectrum. This makes a big difference for the dynamic energy transfer between light and the vibrating molecule: Depending on the temporal structure of the laser pulse, the molecule can then absorb and release energy several times during the excitation.

In order to understand exactly which contributions are decisive for the energy transfer, the researchers have developed a supercomputer-based quantum chemical model. This can explain the results of the measurements without the aid of measured values. “This allows us to artificially switch off individual effects such as the collisions of the vibrating molecules with their environment, or even the dielectric properties of the environment, and thus elucidate their influence on the energy transfer,” explains Martin Peschel, one of the first authors of the study.

In the end, the energy re-emitted during the decaying light field oscillations is decisive for how much information can be obtained from a spectroscopic measurement. The work thus makes a valuable contribution to better understanding the efficiency of optical spectroscopies, for example with regard to molecular compositions of fluids or gases, with the objective of improving it further and further.

The research is published in Nature Communications.

Physicists predict the novel entangled states on programmable quantum simulators

Quantum innovations using Rydberg atoms. Credit: Caltech

Quantum science has not only deepened human understanding of the structure of matter and its microscopic interactions, but also introduced a new paradigm of computing and information science—quantum computing and quantum simulation. Quantum informatics research has won the 2022 Nobel Prize in Physics.


Among many quantum computing and simulation platforms, Rydberg Atom Arrays is considered the most promising system to show quantum superiority among many programmable quantum simulator platforms in recent years due to its largest number of qubits and highest experimental accuracy.

Such optical lattices consist of individual neutral alkaline-earth atoms with significant dipole moments trapped in arrays of microscopic dipole traps, which can be optically moved at will to make desired lattice geometry. Each atom can be excited to its Rydberg state, and a pair of excited states interact through their dipole moments via a long-range interaction.

Such Rydberg atom arrays are believed by many to be the system with the highest level of experimental precision and number of qubits in recent years within all platforms for programmable quantum simulators. The observations of quantum phase transitions and the signature of topological orders from Rydberg atom arrays have been reported with tremendous speed.

However, the long-range interaction and the Rydberg blockade mechanism in these optical lattices can have both pros and cons. On the one hand, they give rise to the high precision of experimental quantum control, as mentioned above. Still, on the other hand, they enforce the constraints on modeling the system.

Such quantum-constrained many-body systems are among the hardest to study from theoretical and numerical perspectives. Without a precise theoretical understanding of the complete phase diagrams and novel quantum phases, future experiments will have no guidance to continue.

The obtained phase diagram in this work. Within different phases, the even Z2 quantum spin liquid (QSL) and odd Z2 QSL are topological ordered novel states of matter that are expected to exist in the Rydberg atom array experiments on Kagome lattices. Credit: The University of Hong Kong

Such an apparent conundrum, faced by all scientists in the field, is partially and substantially solved by a joint effort of Research Assistant Professor Zheng Yan and Associate Professor Zi Yang Meng from the Department of Physics, the University of Hong Kong (HKU) and the renowned physicist Professor Subir Sachdev (member of American Academy of Arts and Sciences) from Harvard University and his then student Dr. Rhine Samajdar now Postdoctoral fellow at Princeton University and Dr. Yan-Cheng Wang (Researcher) from Beihang Hangzhou Innovation Institute Yuhang at Hangzhou. Their research work has been published in the recent issue of Nature Communications.

They designed a new triangular lattice quantum dimer model with soft constraints to be as close as possible to experiment conditions and developed the sweeping cluster algorithm for quantum Monte Carlo simulations that could solve such soft-constrained quantum many-body systems efficiently.

Their simulations and  successfully map out the expected phase diagram of Rydberg arrays on the Kagome lattice. They found not only the expected and conventional nematic and stagger types of the solid phases but also the exotic highly entangled Z2 quantum spin liquids (QSL) with large parameter regimes in the phase diagram.

They identify these novel phases by designing non-local measurements of string operators and other physical observables in the quantum Monte Carlo simulations. The difference between QSL and trivial paramagnetic phase is distinguished successfully. The most exciting thing is that a path connecting odd Z2 QSL, trivial paramagnetic (PM) , and even QSL and solid phases has been revealed, which is very useful in guiding the Rydberg arrays experiment.

In addition, they have also studied the dynamics and interactions of the fractional quasiparticles (visons) in the Z2 QSL to give more experimentally probable evidence.

These results highlight the richness of their constrained models derived for Rydberg array systems and exploit various new phases induced by the long-range interactions and Rydberg blockade mechanism.

Physicists reach qubit computing breakthrough

a. Experimental SC circuit of device I with qubits and couplers in a square geometry. The light-grey dashed rectangles represent dimers that constitute the chain with intracoupling Ja, intercoupling Je and small cross-coupling Jx. b. Schematic (upper left) of the dynamics of the collective dimer states |Π〉 and |Π′〉. Numerics of the ratio Δ/Γ as a function of system size L for different ratios of Ja/Je, with Jx/2π in the range of [0.3, 1.2] MHz (lower left). Four-dimensional hypercube in the Hilbert space (right). c. Quantum state tomography for the four-qubit fidelity FA(t) and entanglement entropy SA(t) in a 30-qubit chain for thermalizing initial states, namely, |0101…0110〉 (i) and |01001…100110110〉 (ii), and the QMBS state Π′ (green). The couplings are Ja/2π = 1.5Je/2π ≃ −9 MHz. The inset shows the Fourier transform of the four-qubit fidelity with the peak at ω1/2π ≈ 21 MHz. The dashed grey line in the bottom panel represents the maximal thermal entropy for the subsystem, approaching to 4ln(2). d. Same data as c, but for different couplings, namely, Ja/2π = 2.5Je/2π ≃ −10 MHz from device II and ω′1/2π ≈ 22 MHz. Schematics in c and d illustrate the bipartition of the system. Credit: Arizona State University, Zhejiang University

Researchers from Arizona State University and Zhejiang University in China, along with two theorists from the United Kingdom, have been able to demonstrate for the first time that large numbers of quantum bits, or qubits, can be tuned to interact with each other while maintaining coherence for an unprecedentedly long time, in a programmable, solid state superconducting processor.


Previously, this was only possible in Rydberg atom systems.

In a paper to be published on Thursday, Oct. 13, in Nature Physics, ASU Regents Professor Ying-Cheng Lai, his former ASU doctoral student Lei Ying and experimentalist Haohua Wang, both professors at Zhejiang University in China, have demonstrated a “first look” at the emergence of quantum many-body scarring (QMBS) states as a robust mechanism for maintaining coherence among interacting qubits. Such exotic quantum states offer the appealing possibility of realizing extensive multipartite entanglement for a variety of applications in quantum information science and technology to achieve high processing speed and low power consumption.

“QMBS states possess the intrinsic and generic capability of multipartite entanglement, making them extremely appealing to applications such as quantum sensing and metrology,” explained Ying.

Classical, or binary computing relies on transistors—which can represent only the “1” or the “0” at a single time. In quantum computing, qubits can represent both 0 and 1 simultaneously, which can exponentially accelerate computing processes.

“In quantum information science and technology, it is often necessary to assemble a large number of fundamental information-processing units—qubits—together,” explained Lai. “For applications such as quantum computing, maintaining a high degree of coherence or quantum entanglement among the qubits is essential.

“However, the inevitable interactions among the qubits and environmental noise can ruin the coherence in a very short time—within about ten nanoseconds. This is because many interacting qubits constitute a many-body system,” said Lai.

Key to the research is insight about delaying thermalization to maintain coherence, considered a critical research goal in quantum computing.

“From basic physics, we know that in a system of many interacting particles, for example, molecules in a closed volume, the process of thermalization will arise. The scrambling among many qubits will invariably result in quantum thermalization—the process described by the so-called Eigenstate Thermalization Hypothesis, which will destroy the coherence among the qubits,” said Lai.

According to Lai, the findings moving quantum computing forward will have applications in cryptology, secure communications and cybersecurity, among other technologies.

Changing direction: Research team discovers switchable electronic chirality in an achiral Kagome superconductor

An international research team led by the Department of Microstructured Quantum Matter at the MPSD reports the first observation of switchable chiral transport in a structurally achiral crystal, the Kagome superconductor CsV3Sb5. Their work has been published in Nature.


Whether or not an object is indistinguishable from its mirror image has important consequences for its physical behavior. Say you watch a basketball player in a mirror. The ball, the player and their surroundings are, at first glance, just the same in the mirror as in real life. But if observed closely, some details are different. The ball in the player’s right hand now appears in their left hand in the mirror. While the mirror image still shows the same hand, it has clearly changed from a left to a right hand or vice versa. Many other physical objects also have mirror images that differ in a key aspect, just like hands, which is why scientists call them handed or chiral (from Greek χϵρι = hand). Others, like the ball, cannot be distinguished from their mirror image, which makes them achiral.

Chirality is one of the most fundamental geometric properties and plays a special role in biology, chemistry and physics. It can cause surprising effects: One version of the carvone molecule, for example, produces a spearmint smell but its chiral—mirrored—equivalent smells of caraway.

In material science, one distinguishes between crystals in which the periodic arrangement of the atoms is chiral or not. If it is, the electrons and electric currents flowing within it must also differ somehow from their mirror image, a property that can lead to exotic responses and novel applications. One example is a diode-like effect where the electric currents flowing from left to right are different from those flowing right to left, a property called electronic magneto-chiral anisotropy (eMChA). So far, this phenomenon has only been found in structurally chiral crystals.

Now, however, an international research team has reported the first observation of this chiral transport in a structurally achiral crystal, the Kagome superconductor CsV3Sb5. The team involved scientists from the MPSD and the Max Planck Institute for Chemical Physics of Solids (Germany), EPFL and the University of Zurich in Switzerland, the University of the Basque Country (Spain) and Qingdao University in China.

The quantum puzzle is as simple as it is deep: If the atomic positions in the crystal are just the same as in their mirror image, how is it possible that its electrons are not? Clearly a novel mechanism beyond a simple shape effect as in our hands must be at play. Unlike structural chirality, which is as firmly imprinted in a crystal as it is in a human hand, this new electronic chirality can be switched using magnetic fields. Switchable chirality has never before been observed and may well find its application in future technology.

It is clear that this unusual behavior is directly linked to the strong electronic interactions. The team proposes a model in which the electrons arrange themselves in patterns that violate mirror symmetry, even though the atoms are arranged symmetrically.

CsV3Sb5 is already known for many such interacting electronic structures, such as the formation of an unconventional chiral charge order featuring a tantalizing charge modulation. These chiral electronic structures may rotate spontaneously, causing an orbital magnetic response associated to a behavior known as “loop currents,” as described by C. Mielke et al., Nature 2022.

CsV3Sb5 appears to be a fantastic sandbox to probe correlated quantum phenomena, including the first example of switchable electronic chirality. The next steps include increasing the operational range from cryogenic to room temperature and enhancing the magnitude of this response. Clearly, much more is to come from interacting systems on geometrically frustrated lattices.